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Reactivity of Zirconium Complexes Incorporating Asymmetrically Substituted ansa Ligands and Their Use as Catalysts in Olefin Polymerization. X-ray Crystal Structures of [Me 2 Si(η 5 -C 5 Me 4 )(η 5 -C 5 H 3 R)]ZrCl 2 (R = Et, i Pr)

✍ Scribed by Antiñolo, Antonio; López-Solera, Isabel; Otero, Antonio; Prashar, Sanjiv; Rodríguez, Ana M.; Villaseñor, Elena

Book ID
126240746
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
119 KB
Volume
21
Category
Article
ISSN
0276-7333

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✍ Antonio Antiñolo; Rafael Fernández-Galán; Beatriz Gallego; Antonio Otero; Sanjiv 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 183 KB 👁 2 views

## Abstract The monoalkyl complexes [Zr{Me~2~Si(η^5^‐C~5~Me~4~)(η^5^‐C~5~H~3~R)}(R′)Cl] [R = Me, R′ = CH~2~Ph (1); R = Me, R′ = CH~2~SiMe~3~ (2); R = __i__Pr, R′ = CH~2~Ph (3); R = __i__Pr, R′ = CH~2~SiMe~3~ (4); R = SiMe~3~, R′ = CH~2~Ph (5); R = SiMe~3~, R′ = CH~2~SiMe~3~ (6)] have been synthesiz