## Abstract Dicarbonyl(η^5^‐cyclopentadienyl)cobalt(I) (**1**) reacts with the electron‐poor alkyne bis(__tert__‐butylsulfonyl)acetylene to give the corresponding cyclobutadiene complex **6**, whereas the reaction of [CpCo(CO)~2~] with dimethyl acetylenedicarboxylate yields the cyclopentadienone co
✦ LIBER ✦
Reactivity of the [η2-Bis(tert-butylsulfonyl)acetylene](carbonyl)(η5-cyclopentadienyl)cobalt Complex Towards Electron-Rich and -Poor Acetylenes
✍ Scribed by Avijit Goswami; Tobias H. Staeb; Frank Rominger; Rolf Gleiter; Walter Siebert
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 106 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-1948
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The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,