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Reactivity of the [η2-Bis(tert-butylsulfonyl)acetylene](carbonyl)(η5-cyclopentadienyl)cobalt Complex Towards Electron-Rich and -Poor Acetylenes

✍ Scribed by Avijit Goswami; Tobias H. Staeb; Frank Rominger; Rolf Gleiter; Walter Siebert


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
106 KB
Volume
2005
Category
Article
ISSN
1434-1948

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## Abstract Dicarbonyl(η^5^‐cyclopentadienyl)cobalt(I) (**1**) reacts with the electron‐poor alkyne bis(__tert__‐butylsulfonyl)acetylene to give the corresponding cyclobutadiene complex **6**, whereas the reaction of [CpCo(CO)~2~] with dimethyl acetylenedicarboxylate yields the cyclopentadienone co

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