Reactivity of the Cluster Core of Ruthenaboranes Toward Phosphorus Compounds
β Scribed by L. N. Pangan; M. Shimoi; H. Kawakami; Y. Kawano
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 7 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
Trialkyl phosphites (l), dialkyl phenylphosphinites (2), and alkyl diphenylphosphonites (3) as well as 2-phenyl-1,3,2-dioxaphospholan (4a) and 2-phenyl-l,3,2-dioxaphosphorinan (4b) give rise to dediazoniation of ar-
Rate constants for a series of alcohols, ethers, and esters toward the sulfate radical (SO 4 Οͺ ) have been directly determined using a laser photolysis set-up in which the radical was produced by the photodissociation of peroxodisulfate anions. The sulfate radical concentration was monitored by foll