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Reactivity of synthetic expandable fluorine mica with titania sol: Effects of layer charge and interlayer cation species

✍ Scribed by Kunio Kitajima; Futoshi Kuniyoshi


Book ID
104296688
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
569 KB
Volume
101-103
Category
Article
ISSN
0167-2738

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✦ Synopsis


The reactivity of synthetic expandable fluorine micas [M,Mg,_XLi,(Si,O,,)F, (M = Li, Na, K), x = 0.4, 0.5, 0.6, 0.81 with titania sol was investigated. The interlayer cation species of host micas have a strong effect on the complex formation, resulting in different titania contents and surface areas of titania-pillared micas in the order K' < Na+ < Li +. This is due to the difference in the expandability of host micas. The layer charge (x) also affects the complex formation. The Na,-series gave a maximum of titania content at x = 0.6.