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Reactivity of Schiff Base Manganese(III) Complexes with Different Pendants toward the Hydrolysis of p-Nitrophenyl Picolinate

✍ Scribed by Weidong Jiang; Xiyang He; Ying Wang; Bin Xu; Jianzhang Li; Fuan Liu

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 606 KB
Volume: 29
Category: Article
ISSN: 0256-7660
DOI: 10.1002/cjoc.201180358

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## Abstract Molecular‐orbital calculations have been performed for the conjugate base __cis__‐[Co(NH~3~)~4~(NH~2~)Cl]^+^ and __trans__‐[M(NH~3~)~4~(NH~2~)Cl]^+^ (M = Cr^III^, Co^III^, and Rh^III^), the hexacoordinated intermediates __cis‐__ and __trans__‐[Co(NH~3~)~4~(NH~2~)…Cl]^+^, the square‐pyra