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Reactivity of ruthenium carbonyl carboxylates under hydroformylation conditions

โœ Scribed by Antonella Salvini; Piero Frediani; Donella Rovai; Mario Bianchi; Franco Piacenti


Publisher
Elsevier Science
Year
1994
Weight
966 KB
Volume
89
Category
Article
ISSN
0304-5102

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Photochemical Carbonylation of Ethane un
โœ Thomas E. Bitterwolf; Dinara Lukmanova Kline; John C. Linehan; Clement R. Yonker ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 72 KB

Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe ) Cl] photochemically transforms ethane to propionaldehyde in single-phase mixtures of ethane and in carbon dioxide/ethane single phases [Eq. (1)]. A side reaction of carbon dioxide with the catalyst to give OPMe and [Rh(CO) (PMe )Cl] or [Rh