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Reactivity of Radical Cations. Effect of Radical Cation and Alkene Structure on the Absolute Rate Constants of Radical Cation Mediated Cycloaddition Reactions 1

✍ Scribed by Schepp, Norman P.; Johnston, Linda J.

Book ID
121367246
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
368 KB
Volume
118
Category
Article
ISSN
0002-7863

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## Abstract The structure and reactivity of the cysteine methyl ester radical cation, CysOMe^.+^, have been examined in the gas phase using a combination of experiment and density functional theory (DFT) calculations. CysOMe^.+^ undergoes rapid ion–molecule reactions with dimethyl disulfide, allyl