Reactivity of Alkynes Containing α-Hydro
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Javier A. Cabeza; Ignacio del Río; Santiago García-Granda; Lorena Martínez-Ménde
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Article
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2005
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John Wiley and Sons
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English
⚖ 309 KB
## Abstract The reactions of the hydrido–triruthenium cluster complex [Ru~3~(μ‐H)(μ~3~‐__κ__^2^‐HNNMe~2~)(CO)~9~] (1; H~2~NNMe~2~=1,1‐dimethylhydrazine) with alkynes that have α‐hydrogen atoms give trinuclear derivatives containing edge‐bridging allyl or face‐capping alkenyl ligands. Under mild con