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Reactivity of Protons, Tertiary Stannanes, and Alkynes with a Triruthenium Dihydrido Cluster Containing a Face-Capping NHC Ligand

✍ Scribed by Cabeza, Javier A.; del Río, Ignacio; Fernández-Colinas, José M.; Sánchez-Vega, M. Gabriela


Book ID
126064351
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
131 KB
Volume
28
Category
Article
ISSN
0276-7333

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## Abstract The reactions of the hydrido–triruthenium cluster complex [Ru~3~(μ‐H)(μ~3~‐__κ__^2^‐HNNMe~2~)(CO)~9~] (1; H~2~NNMe~2~=1,1‐dimethylhydrazine) with alkynes that have α‐hydrogen atoms give trinuclear derivatives containing edge‐bridging allyl or face‐capping alkenyl ligands. Under mild con

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