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Reactivity of O-alkyl O-p-nitrophenyl chlorometylphosphonate in aqueous micellar solution of surfactants

✍ Scribed by L.Ya. Zakharova; L.A. Kudryavtseva; R.A. Shagidullina

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
277 KB
Volume
91
Category
Article
ISSN
0167-7322

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✦ Synopsis

The comparison of the reactivity of 0-alkyl O-p-nittophenyl chlorometylphosphonates in two processes -basic hydrolysis and the reaction with o-aminomethyl phenols (Ah@) meals that both in the absence of cetylpyridininm bromide (CPB) and in the CPB micelles nucleophilic activity of the hydroxide-ion is much higher (by 2 orders) than that of AMP. III the basic hydrolysis the concentration factor is found to play a more significant role in comparison with the reaction of the substrate with AMP due to the higher binding constants of the reagents. A variation in the substrate binding constant depending on the reaction medium and the reaction type was revealed.

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