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Reactivity of N-phenacyloxycarbamates and related systems in the presence of bases: study of a new [1,2] anionic rearrangement

✍ Scribed by Consonni, Piero; Favara, Duccio; Omodei-Sal�, Amedeo; Bartolini, Giuseppe; Ricci, Alfredo


Book ID
120073839
Publisher
Royal Society of Chemistry
Year
1983
Tongue
English
Weight
821 KB
Volume
7
Category
Article
ISSN
1472-779X

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Reactivity studies of ethyl(Z)-N-(2-amin
✍ M. Joséalves; M. Alice Carvalho; M. Fernanda; J. R. P. Proença; Brian L. Booth 📂 Article 📅 2000 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 548 KB

## Abstract The reaction of ethyl(Z)‐__N__‐(2‐amino‐1,2‐dicyanovinyl)formimidate **6** with carbonyl compounds in the presence of triethyl amine occurs with formation of the Schiff s base and intramolecular hydrolysis of the adjacent cyano group to give the alkylideneamino derivatives **8a‐f**. Whe