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Reactivity of N-1-(2,2-dichloroalkylidene) amides

✍ Scribed by Norbert De Kimpe; Roland Verhé; Laurent De Buyck; Walter Dejonghe; Niceas Schamp

Book ID
102773451
Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
582 KB
Volume
85
Category
Article
ISSN
0037-9646

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## Abstract Treatment of N‐1‐(2, 2‐dichloroalkylidene)t.butylamines 1a‐c with excess methanolic sodium methoxide under reflux afforded mainly a mixture of α‐methoxy‐α,β‐unsaturated aldimines 2a‐c and the rearrangement products 3, besides small amounts of N‐t.butyl 2‐chloroamides 4 and N‐t.butyl 2‐c