Reactivity of monoenic and conjugated diene systems present in unsaturated olefin terpolymers—I. Reactions with t-butoxy radicals (CH3)3 CO•

Reactivity of monoenic and conjugated di

Reactivity of monoenic and conjugated diene systems present in unsaturated olefin terpolymers—II. Reactions with methyl radicals

✍ A Faucitano; H Atarot; F Faucitano Martinotti; V Comincioli; S Cesca 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 670 KB

The experimental rate constants for the reactions of methyl radicals with model compounds simulating ethylidene-norbornene (ENB), methylene-norbornene (MNB) and isopropylidene-dicyclopentadiene (IPDCP} units in EPDM and EPTM elastomers are reported. These constants, as well as others reported in a p