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Reactivity of lithium trimethylsilyldiazomethane and diazomethane toward the 5,6-double bond of uracil and uridine derivatives

✍ Scribed by Raffaele Saladino; Luigi Stasi; Claudia Crestini; Rosario Nicoletti; Maurizio Botta

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
558 KB
Volume
53
Category
Article
ISSN
0040-4020

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✦ Synopsis

The reaction of lithium trimethylsilyldiazomethane [TMS(Li)N2] with uracil and uridine derivatives is reported; this provides a general method for the synthesis of several new annulated and fused heterocyclic systems. The unexpected cycloaddition of diazomethane (CH2N 2) to the C-5,6 double bond of 5-nitrouracil and 5-nilrouridine derivatives is also reporled.

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