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Reactivity of ketene dithiolates toward alkyl bromides

โœ Scribed by Venkatapuram Padmavathi; Guda Dinneswara Reddy; Gali Sudhakar Reddy; Konda Mahesh; Adivireddy Padmaja


Publisher
Journal of Heterocyclic Chemistry
Year
2011
Tongue
English
Weight
74 KB
Volume
48
Category
Article
ISSN
0022-152X

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โœฆ Synopsis


Abstract

The reactivity of barbituric/thiobarbituric ketene dithiolates with bromoacetic ester and phenacyl bromide is studied. J. Heterocyclic Chem., (2011).


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Reactivity of tert-butoxy radicals towar
โœ M. V. Encinas; E. A. Lissi; C. Majmud; A. F. Olea ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 326 KB

Rate constants for the reactions of tert-butoxy radicals (generated by the thermal decomposition of di-tert-butylperoxyoxalate) with several sulfur containing compounds have been measured a t 310 K in benzene. Hexanethiol ( k = 6.5 x lO'M-'s-') reacts considerably faster than alkyl sulfides and disu