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Reactivity of hypervalent iron with biological compounds

✍ Scribed by Dr. Benon H. J. Bielski

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
419 KB
Volume
32
Category
Article
ISSN
0364-5134

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A hypervalent arsorane with an As-Fe bond [6: Rf 2 As\*FeCp(CO) 2 (Rf: o-C 6 H 4 C(CF 3 ) 2 O-)] was synthesized by the reaction of the arsoranide anion (4-Et 4 N: Rf 2 As\* -Et 4 N ‫ם‬ ) with CpFe(CO) 2 I (5) in the presence of AgBF 4 . Diastereomeric arsoranes {7a and 7b: Rf 2 As\*Fe\*Cp(CO)(PPh 3