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Reactivity of Hydrogen Atoms toward Some Cobalt(III) Complexes in Aqueous Solutions 1

✍ Scribed by Halpern, Jack; Rabani, Joseph

Book ID
120537742
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
736 KB
Volume
88
Category
Article
ISSN
0002-7863

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The Reactivity of the Pentacyano(Ξ·1-Diox
The Reactivity of the Pentacyano(Ξ·1-Dioxygen)cobaltate(III) Ion in Aqueous Solution
✍ Michel H. Gubelmann; StΓ©phane Riittimann; Bernard Bocquet; Alan F. Williams πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 German βš– 556 KB

The mononuclear q l-dioxygen complex [CO(CN),O,]~-(A) decomposes in aqueous solution to the hydroxocomplex [Co(CN),OHI3-(B) and the hydroperoxo complex [Co(CN),O0Hl3-(C). The mechanism involves partial dissociation of A to give [CO(CN),]~-(E) which binds with unreacted A to give the q':ql-peroxo com