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Reactivity of Grubbs' Catalysts with Urea- and Amide-Substituted Olefins. Metathesis and Isomerization

✍ Scribed by Formentín, Pilar; Gimeno, Nélida; Steinke, Joachim H. G.; Vilar, Ramón

Book ID
126092671
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
85 KB
Volume
70
Category
Article
ISSN
0022-3263

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✍ Patrycja Żak; Cezary Pietraszuk; Bogdan Marciniec 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 399 KB

Efficient cross-metathesis (CM) of linear and cyclic vinyl-substituted oligosiloxanes with selected olefins in the presence of Grubbs type ruthenium alkylidene complexes is described. Treatment of styrene or 4-substituted styrenes with vinyl group at siloxane skeleton results in the formation of res