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Reactivity of functional groups toward H+and SiMe3+ions

✍ Scribed by V. I. Kadentsev; A. A. Stomakhin; N. G. Kolotyrkina; O. S. Chizhov

Book ID
105595403
Publisher
Springer
Year
2000
Tongue
English
Weight
139 KB
Volume
49
Category
Article
ISSN
1573-9171

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Migration tendencies of functional group
Migration tendencies of functional groups toward sigmatropic rearrangement in 3,3-disubstituted 3H-pyrazoles
✍ Peter Sciess; Henri Stalder πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 French βš– 257 KB

Disubstituted 3H-pyrazoles la -e aromatise through an intramolecular sigmatropic 1,5-(1,2-)shift of one ofthe quaternary groups. From a kinetic study of the uncatalysed and of the acid catalysed isomerisation reaction migration tendencies of functional groups in sigmatropic rearrangement toward neut