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Reactivity of Diarylmethane Derivatives in Supercritical Alcohols Media: Reduction of Diarylmethanols and Diaryl Ketones to Diarylmethanes Using Supercritical 2-Propanol.

โœ Scribed by Bunpei Hatano; Daisuke Kubo; Hideyuki Tagaya

Book ID
101995110
Publisher
John Wiley and Sons
Year
2007
Weight
27 KB
Volume
38
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

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๐Ÿ“œ SIMILAR VOLUMES

Novel direct reduction of diaryl ketones
Novel direct reduction of diaryl ketones to diarylmethanes using supercritical 2-propanol
โœ Bunpei Hatano; Hideyuki Tagaya ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 92 KB

We found that diaryl ketones reduce directly to diaryl alkanes under supercritical 2-propanol. This method was applied to one-pot synthesis of anthracene from anthraquinone derivatives by the addition of sulfur in excellent yields.