𝔖 Bobbio Scriptorium

✦ LIBER ✦

Reactivity of cyclopalladated compounds. 19. Regioselective formation of .eta.3-allylic ligands via the reaction of alkynes with [cyclic] [{Pd(CH(SiMe3)C6H4NMe2-2)(.mu.-Cl)}2]

✍ Scribed by Maassarani, Fida.; Pfeffer, Michel.; Van Koten, Gerard.

Book ID: 127022731
Publisher: American Chemical Society
Year: 1989
Tongue: English
Weight: 506 KB
Volume: 8
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om00106a003

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Addition of small molecules to (.eta.-C5

Addition of small molecules to (.eta.-C5H5)2Rh2(CO)(CF3C2CF3). 6. Formation of the .mu.-alkylidene complexes (.eta.-C5H5)2Rh2(.mu.-CO)(.mu.-CHR)(.mu.-CF3C2CF3) (R = CO2Et, SiMe3, CF3, or CH:CH4) and coupling reactions of the alkyne and carbene ligands within these complexes. X-ray crystal structure of (.eta.-C5H5)2Rh2(CO){C(CF3)C(CF3)CH(CO2Et)}

✍ Dickson, Ron S.; Fallon, Gary D.; Jenkins, Susan M.; Nesbit, Rhonda J. 📂 Article 📅 1987 🏛 American Chemical Society 🌐 English ⚖ 944 KB

Cyclopalladated compounds derived from a

Cyclopalladated compounds derived from a [C,N,S] terdentate ligand: synthesis, characterization and reactivity. Crystal and molecular structures of [Pd{2-ClC6H3C(H)NCH2CH2SMe}(Cl)] and [{Pd[2-ClC6H3C(H)NCH2CH2SMe]}2{µ-Ph2P(CH2)4PPh2}][CF3SO3]2

✍ Fernández, Alberto; Vázquez-García, Digna; Fernández, Jesús J.; López-Torres, Ma 📂 Article 📅 2002 🏛 Royal Society of Chemistry 🌐 English ⚖ 238 KB

Reactivity of cyclopalladated compounds.

Reactivity of cyclopalladated compounds. 9. Synthesis of trinuclear compounds with a carbonylmetalate anion as a bridging unit between two palladium(II) centers. Crystal and molecular structure of cyclo-[(PdMe2NCH2C6H4)2(.mu.-Cl)(.mu.-Co(CO)4)] and cyclo-[(PdMe2NCH2C6H4)2(.mu.-Cl)[.mu.-Mo(CO)3(.eta.5-C5H5)]]

✍ Pfeffer, Michel; Fischer, Jean; Mitschler, Andre 📂 Article 📅 1984 🏛 American Chemical Society 🌐 English ⚖ 973 KB

Binuclear complexes of nickel with the b

Binuclear complexes of nickel with the bridging o-CH2C6H4 ligand: synthesis and reactions. X-ray crystal structure of [cyclic] trans-(Me3P)2BrNi[C(O)C6H4CH2-o]NiBr(PMe3), a complex containing a bridging .mu.2-.eta.1:.eta.1-aroyl ligand

✍ Campora, Juan; Gutierrez, Enrique; Monge, Angeles; Poveda, Manuel L.; Carmona, E 📂 Article 📅 1992 🏛 American Chemical Society 🌐 English ⚖ 947 KB

Reaction of (.mu.-H)2Os3(CO)10 with (.et

Reaction of (.mu.-H)2Os3(CO)10 with (.eta.5-C5H5)(CO)2W.tplbond.CC6H4CH3. Crystal structure of (.eta.5-C5H5)WOs3(CO)11[C(O)CH2C6H4CH3]..apprx.0.5CCl4, a complex with a triply bridging (.mu.3,.eta.2) acyl ligand on the surface of a triangulated rhomboidal metal cluster

✍ Park, Joon T.; Shapley, John R.; Churchill, Melvyn Rowen; Bueno, Clifford 📂 Article 📅 1983 🏛 American Chemical Society 🌐 English ⚖ 792 KB

Study of the system [Rh(C2H4)2Cl]2-P[N(C

Study of the system [Rh(C2H4)2Cl]2-P[N(CH3)2]3 and evidence of N,N,N',N'-tetramethylethylenediamine formation via intramolecular N(CH3)2 transfer to .eta.2-C2H4. Reaction with carbon dioxide of the rhodium complexes

✍ Aresta, M.; De Fazio, M.; Bruno, P. 📂 Article 📅 1982 🏛 American Chemical Society 🌐 English ⚖ 500 KB