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Reactivity of coordinated nitrosyls. IV. One-electron reactivity of ruthenium(III) nitrosylpentaammine ion in aqueous solution

✍ Scribed by Armor, John N.; Hoffman, Morton Z.


Book ID
127021033
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
515 KB
Volume
14
Category
Article
ISSN
0020-1669

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The mononuclear q l-dioxygen complex [CO(CN),O,]~-(A) decomposes in aqueous solution to the hydroxocomplex [Co(CN),OHI3-(B) and the hydroperoxo complex [Co(CN),O0Hl3-(C). The mechanism involves partial dissociation of A to give [CO(CN),]~-(E) which binds with unreacted A to give the q':ql-peroxo com