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Reactivity of Chalcogenostannate Salts: Unusual Synthesis and Structure of a Compound Containing Ternary Cluster Anions [Co4(μ4-Se)(SnSe4)4]10−

✍ Scribed by Christian Zimmermann; Maike Melullis; Stefanie Dehnen


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
121 KB
Volume
41
Category
Article
ISSN
0044-8249

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Bis(disulfide) bridged Nb(+4) cluster halide complexes [Nb 2 S 4 X 8 ] 4± (X = Cl, Br) were prepared by acid hydrolysis of [Nb 2 S 4 (NCS) 8 ] 4± in concentrated aqueous HCl or HBr, solution from which they can be isolated as double salts Cs 5 [Nb 2 S 4 X 8 ]X (X = Cl, 1; X = Br, 2). The crystal st