Reactivity of an Aminopyridine [LMn II ] 2+ Complex with H 2 O 2 . Detection of Intermediates at Low Temperature
✍ Scribed by Groni, Sihem; Dorlet, Pierre; Blain, Guillaume; Bourcier, Sophie; Guillot, Régis; Anxolabéhère-Mallart, Elodie
- Book ID
- 120486489
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 562 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0020-1669
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📜 SIMILAR VOLUMES
the radical oxy-Cope rearrangement. [17] For this purpose, the sulfoxide 10 was prepared from norbornenone 8 via the allylic alcohol 9 (the direct synthesis with the procedure of Evans et al. does not work in this particular case). By treating the sulfoxide 10 with Bu 3 SnH and azobisisobutyronitril
## Intermediate product of the reaction of M O O S ~( S ~C N R ~) ~ and PPh3 in dichloroethane has been detected by ESR spectroscopy. Two ESR signals have been observed a t low temperature in the reaction system which was stopped by quenching it in liquid nitrogen. The g values are 2.020 ? 0.001 a