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Reactivity of a Titanium Dinitrogen Complex Supported by Guanidinate Ligands: Investigation of Solution Behavior and a Novel Rearrangement of Guanidinate Ligands

✍ Scribed by Mullins, Sarah M.; Duncan, Andrew P.; Bergman, Robert G.; Arnold, John


Book ID
125935144
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
174 KB
Volume
40
Category
Article
ISSN
0020-1669

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## Abstract The reactions of anhydrous LnCl~3~ (Ln = Y, Nd, Sm, Lu) with two equiv. of sodium __N__,__Nβ€²__‐dicyclohexyl‐__Nβ€²β€²__‐bis(trimethylsilyl)guanidinate Na[(Me~3~Si)~2~NC(NCy)~2~], obtained from Na[N(SiMe~3~)~2~] and the 1,3‐dicyclohexyl‐substituted carbodiimide CyN=C=NCy in THF, yield the mo