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Reactivity of a Phosphido-Niobocene Derivative toward CS 2 and Alkyl Halides to Give Phosphinodithioformato- and Phosphino-Niobocene Complexes: X-ray Crystal Structures of [Nb(η 5 -C 5 H 4 SiMe 3 ) 2 (κ 1 -S-SC(S)(PPh 2 ))(CO)] and [Nb(η 5 -C 5 H 4 SiMe 3 ) 2 (P(I)Ph 2 )(CO)]I 3

✍ Scribed by Antiñolo, Antonio; García-Yuste, Santiago; Otero, Antonio; Pérez-Flores, Juan C.; Reguillo-Carmona, Rebeca; Rodríguez, Ana M.; Villaseñor, Elena


Book ID
126881158
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
165 KB
Volume
25
Category
Article
ISSN
0276-7333

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Synthesis, Structural Characterisation a
✍ Antonio Antiñolo; Iván Dorado; Mariano Fajardo; Andrés Garcés; Isabel López-Sol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3