𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reactivity of a Frustrated Lewis Pair and Small-Molecule Activation by an Isolable Arduengo CarbeneB{3,5-(CF 3 ) 2 C 6 H 3 } 3 Complex

✍ Scribed by Kolychev, Eugene L.; Bannenberg, Thomas; Freytag, Matthias; Daniliuc, Constantin G.; Jones, Peter G.; Tamm, Matthias

Book ID
118754267
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
623 KB
Volume
18
Category
Article
ISSN
0947-6539

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Hydrogen and Amine Activation by a Frust
Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N-Heterocyclic Carbene and B(C6F5)3
✍ Preston A. Chase; Douglas W. Stephan 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 366 KB 👁 1 views

N-Heterocyclic carbenes (NHCs), [1] one class of stable and isolable carbenes, [2] are a well-studied ligand that can often replace phosphines in organometallic complexes, which have found extensive use in catalysis. [3,4] NHCs are also utilized as organocatalysts in their own right, [5][6][7] and t

Addition of small molecules to (.eta.-C5
Addition of small molecules to (.eta.-C5H5)2Rh2(CO)(CF3C2CF3). 6. Formation of the .mu.-alkylidene complexes (.eta.-C5H5)2Rh2(.mu.-CO)(.mu.-CHR)(.mu.-CF3C2CF3) (R = CO2Et, SiMe3, CF3, or CH:CH4) and coupling reactions of the alkyne and carbene ligands within these complexes. X-ray crystal structure of (.eta.-C5H5)2Rh2(CO){C(CF3)C(CF3)CH(CO2Et)}
✍ Dickson, Ron S.; Fallon, Gary D.; Jenkins, Susan M.; Nesbit, Rhonda J. 📂 Article 📅 1987 🏛 American Chemical Society 🌐 English ⚖ 944 KB