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Reactivity of 2-fluoro-5-nitrothiophene towards sodium thiophenoxide and piperidine. Comparison with other 2-halogeno-5-nitrothiophenes

✍ Scribed by Giuseppe Guanti; Sergio Thea; Carlo Dell'Erba; Giuseppe Leandri

Book ID
112123556
Publisher
Journal of Heterocyclic Chemistry
Year
1975
Tongue
English
Weight
396 KB
Volume
12
Category
Article
ISSN
0022-152X

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Solvent polarity and hydrogen bond effects on nucleophilic substitution reaction of 2-bromo-5-nitrothiophene with piperidine
✍ Ali Reza Harifi-Mood; Masoud Rahmati; Mohammad Reza Gholami 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 157 KB

## Abstract The reaction kinetics of 2‐bromo‐5‐nitro thiophene with piperidine was studied in a solvent with a mixture of propan‐2‐ol with methanol and __n__‐hexane at 25°C. The measured rate coefficients of the reaction demonstrated dramatic variations in propan‐2‐ol–__n__‐hexane mixtures and mild