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Reactivity of 17- and 19-electron organometallic complexes. Formation of bent sandwich 19-electron radical cation complexes of ruthenium and osmium

✍ Scribed by S. V. Kukharenko; V. V. Strelets; L. I. Denisovich; M. G. Peterleitner; A. Z. Kreindlin; A. R. Kudinov; M. I. Rybinskaya


Book ID
112389063
Publisher
Springer
Year
1995
Tongue
English
Weight
570 KB
Volume
44
Category
Article
ISSN
1573-9171

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17- to 19-Electron Pentamethylcyclopenta
✍ Dr. Marie-HΓ©lΓ¨ne Desbois; Prof. Didier Astruc πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 English βš– 241 KB

I 11 Under these experimental conditions. UV spectroscopic investigations [lo] have revealed that I and 2 are present as solvent-separated ion pairs. The NMR chemical shifts of 1 and 2 (Table ) largely correspond to those of simple fluorenyllithium systems . The differences in the 6 H and 6C values