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Reactivity model for the Menschutkin reaction. Methylation of alkyl-substituted and heterosubstituted pyridines

✍ Scribed by Schug, John C.; Viers, Jimmy W.; Seeman, Jeffrey I.

Book ID
126888286
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
1008 KB
Volume
48
Category
Article
ISSN
0022-3263

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Measurement of the reactivity of OH with
Measurement of the reactivity of OH with methyl nitrate: Implications for prediction of alkyl nitrate-OH reaction rates
✍ J. S. Gaffney; R. Fajer; G. I. Senum; J. H. Lee πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 474 KB πŸ‘ 1 views

The rate of the gas phase reaction of hydroxyl radical with methyl nitrate has been measured to be (3.4 \* 0.4) x cm3 molecule-' s-' at 298 K using flow discharge/ resonance fluorescence techniques. By means of correlation methods, this rate determination is used to predict a vertical ionization pot