Reactivity and selectivity under microwaves in organic chemistry. Relation with medium effects and reaction mechanisms
✍ Scribed by Loupy, André; Perreux, Laurence; Liagre, Marion; Burle, Karine; Moneuse, Michel
- Book ID
- 125491635
- Publisher
- International Union of Pure and Applied Chemistry
- Year
- 2001
- Tongue
- English
- Weight
- 61 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0033-4545
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AbstractÐA kinetic study of the reactions of (CO) 5 CrvC(OMe)C 6 H 4 X (X4-Cl, 4-F, H, 4-Me, 4-OMe and 4-NMe 2 ) and the respective tungsten carbene complexes with primary aliphatic amines (mainly n-butylamine) in 50% MeCN±50% water (v/v) at 258C is reported. The rate law is complex and shows OH 2 a