Reactivities of sterically hindered styrenes toward addition of free radicals
β Scribed by Huyser, Earl S.; Kim, Leo
- Book ID
- 125974206
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 765 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Radical additions 1 Acrylonitriles 1 Diphenylmethyl radicals / Steric effects Additions of the substituted diphenylmethyl radicals Arl-Ar'CR 2 (R = CMe3, SiMe3, GeMe3, SnMe3, OSiMe3, CF3, CO'Me, CN) to various acrylonitriles CHZ=C(X)CN 3 (X = SMe, SiPr, StBu, OAc, OSiMe,, OSiEt3, OMe, OEt) lead to 1
## Abstract A new dualβparameter of vinyl monomers for the reactivities toward freeβradicals has been evaluated on the basis of kinetic data obtained by the flash photolysis method. As a model reaction system, the reversible addition reactions of the substituted phenylthiyl radicals to vinyl monome