The monoanion of 2-chloropentylphosphonic acid was thermally decomposed in the solid state, and the products of the fragmentation were identified and quantitatively determined. The reaction can involve either the elimination of HCl or the Cl ion and the metaphosphate (HPO 3 ), and it was found that
Reactive state selectivity in photodimerization through micellar counter-ion effects: photodimerization of acenaphthylenes
โ Scribed by V. Ramesh; V. Ramamurthy
- Book ID
- 103493851
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 541 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0047-2670
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Thermal Fragmentation of 2-Chloropentylphosphonic Salts in the Solid State. Counter-Ion Effects on Reactivity and Selectivity. -The nature of the counter ion is found to strongly influence the chemoselectivity, i.e. cleavage of the P-C [โ (II)] vs. cleavage of a C-H bond [โ (III)/(IV)], of the therm
## Abstract In micellar electrokinetic capillary chromatography (MECC) the most widely used surfactant for the pseudostationary phase is sodium dodecyl sulfate (SDS), although other types of surfactants have been investigated. We have synthesized the magnesium salt of dodecyl sulfate (Mg(DS)~2~) in