Reactive Intermediates (MS Investigations in Solution) || Gas Phase Ligand Fragmentation to Unmask Reactive Metallic Species

✍ Scribed by Santos, Leonardo S.

• Publisher: Wiley-VCH Verlag GmbH & Co. KGaA
• Year: 2010
• Tongue: German
• Weight: 262 KB
• Edition: 1
• Category: Article
• ISBN: 3527323511
• DOI: 10.1002/9783527628728.ch6

✦ Synopsis

Scheme 6.2 Formation of organolithium by engineering the carboxylate ligand to be a zwitterion (see Ref. [70]).

CO 2 X CO 2 X -CO 2 -CO 2 CID CID CO 2 X Scheme 6.1 Formation of organoalkalis (X ¼ H, Na, K) by engineering the carboxylate ligand to be a dianion (see Ref. [69]).