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Reactive Cysteine Is Protonated in the Triplet Excited State of the LOV2 Domain in Adiantum Phytochrome3

✍ Scribed by Sato, Yoshiaki; Iwata, Tatsuya; Tokutomi, Satoru; Kandori, Hideki


Book ID
127221627
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
46 KB
Volume
127
Category
Article
ISSN
0002-7863

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Water structural changes in the activati
✍ Dai Nozaki; Tatsuya Iwata; Satoru Tokutomi; Hideki Kandori πŸ“‚ Article πŸ“… 2005 πŸ› Elsevier Science 🌐 English βš– 236 KB

In a plants' blue-light receptor phototropin, LOV domains contain a flavin mononucleotide (FMN) as the chromophore. Illumination of LOV domains produces an adduct formation between C(4a) of FMN and an S-H group of surrounding cysteine in an active S390 state. In this paper, we studied water structur