phenylbenzohydroxamic acid) were determined in perfluorooctanoic acid as a reactive counterion surfactant and also with sodium 1dodecanesulphonate and sodium dodecyl sulphate. The pseudo-first-order rate constants increase with reactive and non-reactive surfactant concentrations. These kinetic resul
Reactive and non-reactive counterion surfactants in water and aqueous acetonitrile
β Scribed by D. C. Berndt; C. A. Rossman; C. L. Hach; D. J. Fillar
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 317 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0538-8066
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β¦ Synopsis
Abstract
Rates of hydrolysis of hydroxamic acids with perfluorooctanoic acid as a reactive counterion surfactant and also with sodium sulfonate surfactants plus HCl have been determined in both water and aqueous acetonitrile solvents. The pseudophase ion exchange model satisfactorily explains the micellar effects for both the reactive and nonβreactive counterion surfactants in both solvent systems.
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