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Reactions on solid supports part I: Novel preparation of α-formyl pyrroles from α-methylpyrroles by oxidation with thallium (III) nitrate on clay

✍ Scribed by Anthony H. Jackson; K.R.Nagaraja Rao; N.Sim Ooi; Esther Adelakun

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 122 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)81758-5

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Evidence is presented to show that the clay-catalysed thallium nitrate oxidation of a-methylpyrroles to a-formylpyrroles involves formation of an intermediate nitrate ester which subsequently undergoes elimination of nitrite,