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Reactions of (η 6 :η 1 -C 6 H 5 CH 2 CH 2 PR 2 )Ru(CH 3 ) 2 (R = Cy, Ph) with [H(Et 2 O) 2 ][B(3,5-C 6 H 3 (CF 3 ) 2 ) 4 ] in the Presence of Carbon Monoxide, Acetylene, Ethylene, and Norbornene

✍ Scribed by Umezawa-Vizzini, Kayo; Lee, T. Randall

Book ID
127060139
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
231 KB
Volume
22
Category
Article
ISSN
0276-7333

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Sequential C−H and C−Ru Bond Formation a
Sequential C−H and C−Ru Bond Formation and Cleavage during the Thermally Induced Rearrangement of Aryl Ruthenium(II) Complexes with [C 6 H 3 (CH 2 NMe 2 ) 2 -2,6] - as a Bidentate η 2 - C,N Coordinated Ligand. The Crystal Structures of the Isomeric Pairs [RuCl{η 6 -C 10 H 14 }{η 2 - C,N -C 6 H 3 (CH 2 NMe 2 ) 2 -2, n }] ( n = 4 or 6) and [Ru(η 5 -C 5 H 5 ){η 2 - C,N -C 6 H 3 (CH 2 NMe 2 ) 2 -2, n }(PPh 3 )] ( n = 4 or 6)
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