Reactions of α,β-unsaturated ketones of the bicyclo[3.3.1]nonane series with nitro alkanes
✍ Scribed by M. M. Krayushkin; V. V. Sevost’yanova; V. N. Yarovenko; I. V. Zavarzin
- Publisher
- Springer
- Year
- 2009
- Tongue
- English
- Weight
- 208 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Treatment of c~-silyl-cc,[~-unsaturated enones, readily preparable as regio-and stereodefined compounds in high yields, with either 2 equiv, oflCl or one equiv, each oflC1 and A1C13 provides the corresponding cc-iodo-a,[3unsaturated enones in high yields.
Amine-catalyzed Diels-Alder reactions of a,b-unsaturated ketones with dienophiles have been developed. Either (S)-1-(2-pyrrolidinylmethyl)pyrrolidine or L-proline catalyzed the in situ-generation and reaction of 2-amino-1,3-dienes to provide cyclohexanone derivatives in good yield (up to 87%) in one