Reactions of (α,α-disubstituted-phenacyl) and (carbethoxy-disubstituted-methyl)triphenylphosphonium halides with grignard reagents
✍ Scribed by Teruaki Mukaiyama; Ryuichiro Yoda; Isao Kuwajima
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 137 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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## Abstract The α‐chloronitroso compounds **1a–1f** were made to react with methyl and phenyl Grignard reagents. N‐methyl and N‐phenyl substituted ketonitrones **2** and **3** were obtained in 48‐78% yield. The structure of these labile nitrones is based on their spectroscopic properties and on the