Reactions of α-Acetylenic Ketones with N-3-Amidinothioureas. Part 1. Synthesis and Properties of New Derivatives of 1,3-Thiazine.
✍ Scribed by T. E. Glotova; N. I. Protsuk; L. V. Kanitskaya; G. V. Dolgushin; V. A. Lopyrev
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 18 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Abstract magnified image A series of 1,3‐thiazines has been synthesized by the reactions of __N__‐aroylsubstituted thioureas with ethyl propiolate, dimethyl but‐2‐ynedioate and (__E__)‐1,4‐diphenyl‐but‐2‐ene‐1,4‐dione. The reaction of antipyrinylphenyl thiourea with π‐deficient acetylenic reage
## Abstract Various 2‐alkylthio‐1,3‐thiazine derivatives were synthesized by the reactions of S‐alkylthiocarbamates with α,β‐unsaturated ketones in the presence of BF~3~ · Et~2~O. The thiazine was converted into two isomeric dehydrated products in the presence of a Lewis acid. © 2002 Wiley Periodic