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Reactions of Zirconocene Bis(trimethylsilyl)acetylene Complexes with Fluorinated Pyridines: C–H vs. C–F Bond Activation

✍ Scribed by Ulrike Jäger-Fiedler; Perdita Arndt; Wolfgang Baumann; Anke Spannenberg; Vladimir V. Burlakov; Uwe Rosenthal

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 160 KB
Volume: 2005
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200500145

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The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,