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Reactions of V and Mo with 3,5-Di-tert-butyl-1,2-benzoquinone in Coordinating Solvents

✍ Scribed by S. V. Maslennikov; I. A. Aivaz'yan; G. K. Fukin; V. K. Cherkasov; Yu. A. Kurskii

Book ID: 111607909
Publisher: SP MAIK Nauka/Interperiodica
Year: 2004
Tongue: English
Weight: 101 KB
Volume: 30
Category: Article
ISSN: 1070-3284
DOI: 10.1023/b:ruco.0000040722.76821.86

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## Abstract Treatment of a solution of 9,10‐phenanthrenequinone **4** and cyclooctyne **2** in chloroform with boron trifluoride‐ether affords the quinoid α,β‐unsaturated ketone **5** with loss of carbon monoxide. Reaction of 3,5‐di‐__tert__‐butyl‐__o__‐benzoquinone **9** with cyclooctyne **2** giv