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Reactions of Trimethylphosphane-Supported Cobalt Complexes with Salicylaldimines – Formation and Structures of Cobalt Compounds Containing Salicylaldiminato [N:O] Ligands

✍ Scribed by Xiaoyan Li; Fengli Yu; Hongjian Sun; Liye Huang; Haoqing Hou

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 140 KB
Volume: 2006
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200600489

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✦ Synopsis

Abstract

The reactions of low‐valent cobalt complexes CoMe(PMe~3~)~4~, CoCl(PMe~3~)~3~ and Co(PMe~3~)~4~ with salicylaldimines are described to give tetrahedral complexes 7–12, an octahedral complex 13 and a π‐coordinated imine complex 15. The crystal structures of 13 and 15 are reported. The formation and likely mechanisms are discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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