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Reactions of triiron dodecacarbonyl with alkynyl- and allenyllithium reagents: formation of dinuclear products

✍ Scribed by Seyferth, Dietmar.; Archer, Colin M.; Dewan, John C.


Book ID
127259405
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
629 KB
Volume
10
Category
Article
ISSN
0276-7333

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Triarylphosphines bearing 2-pyridyl or 2-benzothiazyl groups react with organolithium reugents at -78Β°C in THF to afford both coupling products and ligand exchanged triarylphosphines. The ligand coupling and ligand exchange are considered to take place via an intermediate formed by the nucleophilic