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Reactions of Tricarbonyl(sorbaldehyde)iron with Carbanions: A Repeatable Organometallic Reaction with Fe(CO)3-Migration

✍ Scribed by Dipl.-Chem. Andreas Hafner; Prof. Dr. Wolfgang von Philipsborn; Priv.-Doz. Dr. Albrecht Salzer


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
217 KB
Volume
24
Category
Article
ISSN
0044-8249

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A kinetic study of the displacement of cycloheptatriene from I($-C,H8)M(CO)J (M = 0, MO. W) by benzonitrile shows unusual changes in rate law down the triad. While the chromium complex obeys the second-order rate law Rate = k[complex] [RCN] , the molybdenum species follows the third-order law Rate =