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Reactions of tri-n-butyltin hydride with diorganotin dichlorides

✍ Scribed by Albert K. Sawyer; Joyce E. Brown; George S. May

Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
229 KB
Volume
11
Category
Article
ISSN
0022-328X

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πŸ“œ SIMILAR VOLUMES

The free-radical reaction of tri-n-butyl
The free-radical reaction of tri-n-butyltin hydride with disulfides
✍ J. Spanswick; K. U. Ingold πŸ“‚ Article πŸ“… 1970 πŸ› John Wiley and Sons 🌐 English βš– 477 KB

The kinetics and absolute rate constants for the free-radical chain reaction of tri-nbutyltin hydride with di-t-butyl disulfide have been measured in cyclohexane at 30". The rate controlling step for chain propagation involves the cleavage of the disulfide bond by an attacking tributyltin radical. T

The free-radical reaction of tri-n-butyl
The free-radical reaction of tri-n-butyltin hydride with peroxides
✍ J. L. Brokenshire; K. U. Ingold πŸ“‚ Article πŸ“… 1971 πŸ› John Wiley and Sons 🌐 English βš– 744 KB

## Abstract Rate constants for the tri‐__n__‐butyltin radical (**Sn Β·**) induced decomposition of a number of peroxides have been measured in benzene at 10Β°C. The values range from ∼100 __M__^βˆ’1^ sec^βˆ’1^ for di‐__t__‐butyl peroxide to 2.6 Γ— 10^7^ __M__^βˆ’1^ sec^βˆ’1^ for di‐__t__‐butyl diperoxyisophth