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Reactions of transition-metal .sigma.-acetylides. 11. Cycloaddition reactions with 1,1-dicyano-2,2-bis(trifluoromethyl)ethene. X-ray structures of [cyclic] W{C:CPhC(CF3)2C(CN)2}(CO)3(.eta.-C5H5), [cyclic] Mn{C:CPhC(CF3)2C(CN)2}(CO)3(dppe), and [cyclic] Fe{C:CPhC(CF3)2C(CN)2}(CO)2(.eta.-C5H5) and of a hydration product, [cyclic] W{NH:C(OH)C(CN):CCPh:C(CF3)2}(CO)2(.eta.-C5H5).cntdot.H2O

โœ Scribed by Bruce, Michael I.; Liddell, Michael J.; Snow, Michael R.; Tiekink, Edward R. T.

Book ID
126966615
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
958 KB
Volume
7
Category
Article
ISSN
0276-7333

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๐Ÿ“œ SIMILAR VOLUMES

Addition of small molecules to (.eta.-C5
Addition of small molecules to (.eta.-C5H5)2Rh2(CO)(CF3C2CF3). 6. Formation of the .mu.-alkylidene complexes (.eta.-C5H5)2Rh2(.mu.-CO)(.mu.-CHR)(.mu.-CF3C2CF3) (R = CO2Et, SiMe3, CF3, or CH:CH4) and coupling reactions of the alkyne and carbene ligands within these complexes. X-ray crystal structure of (.eta.-C5H5)2Rh2(CO){C(CF3)C(CF3)CH(CO2Et)}
โœ Dickson, Ron S.; Fallon, Gary D.; Jenkins, Susan M.; Nesbit, Rhonda J. ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 944 KB