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Reactions of the hydrogen atom in solution. VI. Addition of hydrogen atoms to substituted benzenes. Use of the Hammett equation for correlating radical reactions

โœ Scribed by Pryor, William A.; Lin, T. H.; Stanley, J. P.; Henderson, R. W.

Book ID
126770399
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
822 KB
Volume
95
Category
Article
ISSN
0002-7863

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Addition of atomic hydrogen to acetylene
Addition of atomic hydrogen to acetylene. Chain reactions of the vinyl radical
โœ Anthony B. Callear; Geoffrey Benedict Smith ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 382 KB

The mun reaction products resulting from the addition of ~tomrc hydrogen to acetylene are shown to be ethylene, l&butadiene, and benzene\_ The mechankm mvolves chain reactions of the vinyl and butadienyl radrals, which regenemte atomic hydrogen\_ Some of the rate psrameters are estimated