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Reactions of the hexaruthenium cluster anions [Ru6C(CO)16]2− and [Ru6(CO)18]2− with Au2{Ph2PCH2PPh2}Cl2: crystal and molecular structures of Ru6C(CO)16Au2{Ph2PCH2PPh2} and Ru5(CO)15Au2{Ph2PCH2PPh2}

✍ Scribed by Philip J. Bailey; Michael A. Beswick; Jack Lewis; Paul R. Raithby; M.Carmen Ramirez de Arellano


Book ID
107812615
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
817 KB
Volume
459
Category
Article
ISSN
0022-328X

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✍ Dr. Francisco J. García Alonso; Dr. Manuel García Sanz; Prof. Victor Riera; Dr. 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 237 KB 👁 1 views

H,-elimination from 3 must also occur [Eq. (e)]."ll Note that this equilibrium involves the same 16-electron species implicated in Equation (c). The product-forming hydrido-ethyl (A) and hydridoethyl ethylene (B) species (Scheme 1) "downstream" of reaction (d) have not been observed under a variety