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Reactions of the dimethylcyclosiloxanes in gas-phase catalytic processes. 1. Rupture of the si-c bonds of octamethylcyclotetrasiloxane by hydrogen chloride

โœ Scribed by M. A. Ezerets; I. I. Khazanov; N. T. Vetrova; K. A. Andrianov

Book ID
112438838
Publisher
Springer
Year
1977
Tongue
English
Weight
380 KB
Volume
26
Category
Article
ISSN
1573-9171

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The gas-phase kinetics of the reaction of 1,1-difluoroiodoethane with hydrogen iodide: The Cโ€“I bond dissociation energy in 1,1-difluoroiodoethane
โœ J. M. Pickard; A. S. Rodgers ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 253 KB

## Abstract The kinetics of gasโ€phase reaction of CH~3~CF~2~I with HI were studied from 496 to 549K and have been shown to be consistent with the following mechanism: equation image A least squares treatment of the data gave where ฮธ = 2.303 __RT__ kcal/mole. The observed activation energy __E__